Aluminium triacetate

Aluminium triacetate
Names
IUPAC name
Aluminium acetate
Other names
Aluminium(III) acetate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.004.868 Edit this at Wikidata
UNII
  • CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Al+3]
Properties
C6H9AlO6
Molar mass 204.114 g·mol−1
Appearance white solid[1]
soluble
Related compounds
Related compounds
Basic aluminium diacetate (hydroxyaluminium diacetate), CAS RN 142-03-0, HOAl(CH
3
CO
2
)
2
[1]
Dibasic aluminium monoacetate (dihydroxyaluminium acetate), CAS RN 7360-44-3, (HO)
2
AlCH
3
CO
2
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Aluminium triacetate, formally named aluminium acetate,[2] is a chemical compound with composition Al(CH
3
CO
2
)
3
. Under standard conditions it appears as a white, water-soluble solid[1] that decomposes on heating at around 200 °C.[3] The triacetate hydrolyses to a mixture of basic hydroxide / acetate salts,[4] and multiple species co-exist in chemical equilibrium, particularly in aqueous solutions of the acetate ion; the name aluminium acetate is commonly used for this mixed system.

It has therapeutic applications for its anti-itching, astringent, and antiseptic properties,[5] and, as an over-the-counter preparation like Burow's solution,[6] it is used to treat ear infections.[7][8] Burow's solution preparations have been diluted and modified with amino acids to make them more palatable for use as gargles for conditions like aphthous ulcers of the mouth.[9] In veterinary medicine, aluminium triacetate's astringency property is used for treating Mortellaro disease in hoofed animals such as cattle.[10]

Aluminium triacetate is used as a mordant agent with dyes like alizarin,[11] both alone and in combination. Together with aluminium diacetate[12] or with aluminium sulfacetate[13] it is used with cotton, other cellulose fibres,[14] and silk.[13] It has also been combined with ferrous acetate to produce different colours.[15]

  1. ^ a b c Cite error: The named reference CRC was invoked but never defined (see the help page).
  2. ^ International Union of Pure and Applied Chemistry (2005). Nomenclature of Inorganic Chemistry IUPAC Recommendations 2005 (PDF). RSC Publishing. ISBN 0854044388.
  3. ^ Cite error: The named reference decomposition was invoked but never defined (see the help page).
  4. ^ Cite error: The named reference OxfordDict was invoked but never defined (see the help page).
  5. ^ Cite error: The named reference NCIt was invoked but never defined (see the help page).
  6. ^ Cite error: The named reference BurowsDrugs.com was invoked but never defined (see the help page).
  7. ^ Cite error: The named reference Otitis1 was invoked but never defined (see the help page).
  8. ^ Cite error: The named reference Otitis2 was invoked but never defined (see the help page).
  9. ^ Cite error: The named reference ApthousUlcer was invoked but never defined (see the help page).
  10. ^ Cite error: The named reference Mortellaro was invoked but never defined (see the help page).
  11. ^ Cite error: The named reference W&B was invoked but never defined (see the help page).
  12. ^ Cite error: The named reference DiacetateMordant was invoked but never defined (see the help page).
  13. ^ a b Cite error: The named reference PbOAc2Prep was invoked but never defined (see the help page).
  14. ^ Cite error: The named reference MordantCellulose was invoked but never defined (see the help page).
  15. ^ Ellis, Catharine (2016). "Transformative Processes". The Weaver's Studio   Woven Shibori. F+W Media, Inc. pp. 83–84. ISBN 9781632503541.[permanent dead link]

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