Ethynyl radical

Ethynyl radical
Structural formula of the ethynyl radical
Structural formula of the ethynyl radical
Spacefill model of ethynyl radical
Spacefill model of ethynyl radical
Names
Preferred IUPAC name
Ethynyl
Identifiers
3D model (JSmol)
1814004
ChEBI
ChemSpider
48916
  • InChI=1S/C2H/c1-2/h1H checkY
    Key: XEHVFKKSDRMODV-UHFFFAOYSA-N checkY
  • InChI=1/C2H/c1-2/h1H
    Key: XEHVFKKSDRMODV-UHFFFAOYAZ
  • C#[C]
  • [C]#C
Properties
C2H
Molar mass 25.030 g·mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

The ethynyl radical (systematically named λ3-ethyne and hydridodicarbon(CC)) is an organic compound with the chemical formula C≡CH (also written [CCH] or C
2
H
). It is a simple molecule that does not occur naturally on Earth but is abundant in the interstellar medium. It was first observed by electron spin resonance isolated in a solid argon matrix at liquid helium temperatures in 1963 by Cochran and coworkers at the Johns Hopkins Applied Physics Laboratory.[1] It was first observed in the gas phase by Tucker and coworkers in November 1973 toward the Orion Nebula, using the NRAO 11-meter radio telescope.[2] It has since been detected in a large variety of interstellar environments, including dense molecular clouds, bok globules, star forming regions, the shells around carbon-rich evolved stars, and even in other galaxies.

  1. ^ Cochran, E. L.; Adrian, F. J.; Bowers, V. A. (1964). "ESR Study of Ethynyl and Vinyl Free Radicals". Journal of Chemical Physics. 40 (1): 213. Bibcode:1964JChPh..40..213C. doi:10.1063/1.1724865.
  2. ^ Tucker, K. D.; Kutner, M. L.; Thaddeus, P. (1974). "The Ethynyl Radical C2H – A New Interstellar Molecule". Astrophysical Journal. 193: L115–L119. Bibcode:1974ApJ...193L.115T. doi:10.1086/181646.

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