Iodine clock reaction

Iodine clock reaction (persulfate variation)

The iodine clock reaction is a classical chemical clock demonstration experiment to display chemical kinetics in action; it was discovered by Hans Heinrich Landolt in 1886.[1] The iodine clock reaction exists in several variations, which each involve iodine species (iodide ion, free iodine, or iodate ion) and redox reagents in the presence of starch. Two colourless solutions are mixed and at first there is no visible reaction. After a short time delay, the liquid suddenly turns to a shade of dark blue due to the formation of a triiodide–starch complex. In some variations, the solution will repeatedly cycle from colorless to blue and back to colorless, until the reagents are depleted.

  1. ^ See:
    • Landolt, H. (1886). "Ueber die Zeitdauer der Reaction zwischen Jodsäure und schwefliger Säure" [On the duration of the reaction between iodic acid and sulfurous acid]. Berichte der Deutschen Chemischen Gesellschaft (in German). 19 (1): 1317–1365. doi:10.1002/cber.188601901293.
    • Landolt, H. (1887). "Ueber die Zeitdauer der Reaction zwischen Jodsäure und schwefliger Säure [Part 2]" [On the duration of the reaction between iodic acid and sulfurous acid]. Berichte der Deutschen Chemischen Gesellschaft (in German). 20 (1): 745–760. doi:10.1002/cber.188702001173.

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