Nitroguanidine

Nitroguanidine
Names
IUPAC name
1-Nitroguanidine
Other names
Picrite
NGu
NQ[1]
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.008.313 Edit this at Wikidata
UNII
  • InChI=1S/CH4N4O2/c2-1(3)4-5(6)7/h(H4,2,3,4) checkY
    Key: IDCPFAYURAQKDZ-UHFFFAOYSA-N checkY
  • InChI=1/CH4N4O2/c2-1(3)4-5(6)7/h(H4,2,3,4)
    Key: IDCPFAYURAQKDZ-UHFFFAOYAN
  • NC(N)=N[N+]([O-])=O
Properties
CH4N4O2
Molar mass 104.07 g/mol
Appearance Colorless crystalline solid
Density 1.77 g/cm3
Melting point 257 °C (495 °F; 530 K)
3.45 g/kg (in water at 25 °C)
Explosive data
Shock sensitivity > 50 J
Friction sensitivity > 350 N
RE factor 1.00
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Explosive
Related compounds
Related compounds
Guanidine
Guanidine nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
checkY verify (what is checkY☒N ?)

Nitroguanidine - sometimes abbreviated NGu - is a colorless, crystalline solid that melts at 257 °C and decomposes at 254 °C. Nitroguanidine is an extremely insensitive but powerful high explosive. Wetting it with > 20 wt.-% water effects desensitization from HD 1.1 down to HD 4.1 (flammable solid).[2] Nitroguanidine is used as an energetic material, i.e., propellant or high explosive, precursor for insecticides, and for other purposes.

  1. ^ Gao, Han; Wang, Qinghua; Ke, Xiang; Liu, Jie; Hao, Gazi; Xiao, Lei; Chen, Teng; Jiang, Wei; Liu, Qiao'e (2017). "Preparation and characterization of an ultrafine HMX/NQ co-crystal by vacuum freeze drying method". RSC Adv. 7 (73): 46229–46235. doi:10.1039/C7RA06646E. ISSN 2046-2069.
  2. ^ United Nations, Transport of Nitroguanidine, wetted, (UN 1336) in flexible IBCs, ST/SC/AC.10/C.3/2006/52, Geneva, 13 April 2006. Accessed at https://www.unece.org/fileadmin/DAM/trans/doc/2006/ac10c3/ST-SG-AC10-C3-2006-52e.pdf

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