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Carbon nanotubes (CNTs) are cylinders of one or more layers of graphene (lattice). Diameters of single-walled carbon nanotubes (SWNTs) and multi-walled carbon nanotubes (MWNTs) are typically 0.8 to 2 nm and 5 to 20 nm, respectively, although MWNT diameters can exceed 100 nm. CNT lengths range from less than 100 nm to 0.5 m.[1]
Individual CNT walls can be metallic or semiconducting depending on the orientation of the lattice with respect to the tube axis, which is called chirality. MWNT's cross-sectional area offers an elastic modulus approaching 1 TPa and a tensile strength of 100 GPa, over 10-fold higher than any industrial fiber. MWNTs are typically metallic and can carry currents of up to 109 A cm−2. SWNTs can display thermal conductivity of 3500 W m−1 K−1, exceeding that of diamond.[2]
As of 2013[update], carbon nanotube production exceeded several thousand tons per year, used for applications in energy storage, device modelling, automotive parts, boat hulls, sporting goods, water filters, thin-film electronics, coatings, actuators and electromagnetic shields. CNT-related publications more than tripled in the prior decade, while rates of patent issuance also increased.[2] Most output was of unorganized architecture. Organized CNT architectures such as "forests", yarns and regular sheets were produced in much smaller volumes.[2] CNTs have even been proposed as the tether for a purported space elevator.[3][4]
Recently, several studies have highlighted the prospect of using carbon nanotubes as building blocks to fabricate three-dimensional macroscopic (>1 mm in all three dimensions) all-carbon devices. Lalwani et al. have reported a novel radical initiated thermal crosslinking method to fabricated macroscopic, free-standing, porous, all-carbon scaffolds using single- and multi-walled carbon nanotubes as building blocks.[5] These scaffolds possess macro-, micro-, and nano- structured pores and the porosity can be tailored for specific applications. These 3D all-carbon scaffolds/architectures may be used for the fabrication of the next generation of energy storage, supercapacitors, field emission transistors, high-performance catalysis, photovoltaics, and biomedical devices and implants.
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