Sodium nitrate

Sodium nitrate
Names
IUPAC name
Sodium nitrate
Other names
Peru saltpeter
Soda niter
cubic niter
Identifiers
3D model (JSmol)
ChEMBL
ChemSpider
ECHA InfoCard 100.028.686 Edit this at Wikidata
EC Number
  • 231-554-3
E number E251 (preservatives)
RTECS number
  • WC5600000
UNII
UN number 1498
  • InChI=1S/NO3.Na/c2-1(3)4;/q-1;+1 checkY
    Key: VWDWKYIASSYTQR-UHFFFAOYSA-N checkY
  • InChI=1/NO3.Na/c2-1(3)4;/q-1;+1
    Key: VWDWKYIASSYTQR-UHFFFAOYAL
  • [Na+].[O-][N+]([O-])=O
Properties
NaNO3
Molar mass 84.9947 g/mol
Appearance White powder or colorless crystals
Odor sweet
Density 2.257 g/cm3, solid
Melting point 308 °C (586 °F; 581 K)
Boiling point 380 °C (716 °F; 653 K) decomposes
73 g/100 g water (0 °C)
91.2 g/100 g water (25 °C)[1][2]
180 g/100 g water (100 °C)
Solubility very soluble in ammonia, hydrazine
soluble in alcohol
slightly soluble in pyridine
insoluble in acetone
−25.6·10−6 cm3/mol
1.587 (trigonal)
1.336 (rhombohedral)
Viscosity 2.85 cP (317 °C)
Structure
trigonal and rhombohedral
Thermochemistry
93.05 J/(mol K)
116 J/(mol K)[3]
−467 kJ/mol[3]
−365.9 kJ/mol
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Harmful (Xn)
Oxidant (O)
GHS labelling:
GHS07: Exclamation markGHS03: Oxidizing
NFPA 704 (fire diamond)
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
3236 mg/kg
Safety data sheet (SDS) ICSC 0185
Related compounds
Other anions
Sodium nitrite
Other cations
Lithium nitrate
Potassium nitrate
Rubidium nitrate
Caesium nitrate
Related compounds
Sodium sulfate
Sodium chloride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Sodium nitrate is the chemical compound with the formula NaNO
3
. This alkali metal nitrate salt is also known as Chile saltpeter (large deposits of which were historically mined in Chile)[4][5] to distinguish it from ordinary saltpeter, potassium nitrate. The mineral form is also known as nitratine, nitratite or soda niter.

Sodium nitrate is a white deliquescent solid very soluble in water. It is a readily available source of the nitrate anion (NO3), which is useful in several reactions carried out on industrial scales for the production of fertilizers, pyrotechnics, smoke bombs and other explosives, glass and pottery enamels, food preservatives (esp. meats), and solid rocket propellant. It has been mined extensively for these purposes.

  1. ^ Haynes, William M. (2016-06-22). CRC Handbook of Chemistry and Physics. CRC Press. ISBN 978-1-4987-5429-3.
  2. ^ "Sodium nitrate". PubChem. Retrieved 11 June 2021.
  3. ^ a b Zumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. p. A23. ISBN 978-0-618-94690-7.
  4. ^ "The Nitrate Towns of Chile". Atlas Obscura. Retrieved 27 May 2019.
  5. ^ Mutic, Anja (26 October 2012). "The ghost towns of northern Chile". Washington Post. Retrieved 27 May 2019.

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