Tetrakis(triphenylphosphine)palladium(0)

Tetrakis(triphenylphosphine)­palladium(0)
3D model of the tetrakis(triphenylphosphine)palladium(0) molecule
Tetrakis(triphenylphosphine)palladium(0)
Names
IUPAC name
Tetrakis(triphenylphosphane)palladium(0)
Other names
TPP palladium(0)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.609 Edit this at Wikidata
EC Number
  • 238-086-9
UNII
  • InChI=1S/4C18H15P.Pd/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
    Key: NFHFRUOZVGFOOS-UHFFFAOYSA-N
  • [Pd-4]([P+](c1ccccc1)(c1ccccc1)c1ccccc1)([P+](c1ccccc1)(c1ccccc1)c1ccccc1)([P+](c1ccccc1)(c1ccccc1)c1ccccc1)[P+](c1ccccc1)(c1ccccc1)c1ccccc1
Properties
C72H60P4Pd
Molar mass 1155.59 g·mol−1
Appearance Bright yellow to chartreuse crystals
Melting point decomposes around 115 °C
Insoluble
Structure
four triphenylphosphine monodentate
ligands attached to a central Pd(0)
atom in a tetrahedral geometry
tetrahedral
0 D
Hazards
GHS labelling:[1]
GHS07: Exclamation mark
Warning
H302, H317, H413
P261, P264, P270, P272, P273, P280, P301+P312, P302+P352, P330, P333+P313, P363, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 1: Must be pre-heated before ignition can occur. Flash point over 93 °C (200 °F). E.g. canola oilInstability (yellow): no hazard codeSpecial hazards (white): no code
2
1
Related compounds
Related complexes
chlorotris(triphenylphosphine)rhodium(I)
tris(dibenzylideneacetone)dipalladium(0)

Tetrakis(triphenylphosphine)platinum(0)
Tetrakis(triphenylphosphine)nickel(0)

Related compounds
triphenylphosphine
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tetrakis(triphenylphosphine)palladium(0) (sometimes called quatrotriphenylphosphine palladium) is the chemical compound [Pd(P(C6H5)3)4], often abbreviated Pd(PPh3)4, or rarely PdP4. It is a bright yellow crystalline solid that becomes brown upon decomposition in air.

  1. ^ "Tetrakis(triphenylphosphine)palladium". pubchem.ncbi.nlm.nih.gov.

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