In condensed matter and atomic physics, Van Vleck paramagnetism refers to a positive and temperature-independent contribution to the magnetic susceptibility of a material, derived from second order corrections to the Zeeman interaction. The quantum mechanical theory was developed by John Hasbrouck Van Vleck between the 1920s and the 1930s to explain the magnetic response of gaseous nitric oxide (NO) and of rare-earth salts.[1][2][3][4] Alongside other magnetic effects like Paul Langevin's formulas for paramagnetism (Curie's law) and diamagnetism, Van Vleck discovered an additional paramagnetic contribution of the same order as Langevin's diamagnetism. Van Vleck contribution is usually important for systems with one electron short of being half filled and this contribution vanishes for elements with closed shells.[5][6]
- ^ Van Vleck, John Hasbrouck (1932). The Theory of Electric and Magnetic Susceptibilities. Clarendon Press.
- ^ Van Vleck, J. H. (1928-04-01). "On Dielectric Constants and Magnetic Susceptibilities in the New Quantum Mechanics Part III—Application to Dia- and Paramagnetism". Physical Review. 31 (4): 587–613. Bibcode:1928PhRv...31..587V. doi:10.1103/PhysRev.31.587. ISSN 0031-899X.
- ^ van Vleck, John H. (1977). "John H. van Vleck Nobel Lecture". Nobel Prize. Retrieved 2020-10-18.
- ^ Anderson, Philip W. (1987). John Hasbrouck Van Vleck (PDF). Washington D.C: National Academy of Sciences.
- ^ Marder, Michael P. (2010-11-17). Condensed Matter Physics. John Wiley & Sons. ISBN 978-0-470-94994-8.
- ^ Nolting, Wolfgang; Ramakanth, Anupuru (2009-10-03). Quantum Theory of Magnetism. Springer Science & Business Media. ISBN 978-3-540-85416-6.
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