Cluster expansion

In statistical mechanics, the cluster expansion (also called the high temperature expansion or hopping expansion) is a power series expansion of the partition function of a statistical field theory around a model that is a union of non-interacting 0-dimensional field theories. Cluster expansions originated in the work of Mayer & Montroll (1941). Unlike the usual perturbation expansion which usually leads to a divergent asymptotic series, the cluster expansion may converge within a non-trivial region, in particular when the interaction is small and short-ranged.

The cluster expansion coefficients are calculated by intricate combinatorial counting. See [1] for a tutorial review.

  1. ^ Andersen, Hans C. (1977), Berne, Bruce J. (ed.), "Cluster Methods in Equilibrium Statistical Mechanics of Fluids", Statistical Mechanics: Part A: Equilibrium Techniques, Boston, MA: Springer US, pp. 1–45, doi:10.1007/978-1-4684-2553-6_1, ISBN 978-1-4684-2553-6, retrieved June 27, 2024

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