Cobalt(II) sulfate

Cobalt(II) sulfate
Cobalt(II) sulfate Xray
Cobalt(II) sulfate Xray
Names
IUPAC name
Cobalt(II) sulfate
Other names
Cobaltous sulfate
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.030.291 Edit this at Wikidata
EC Number
  • 233-334-2
KEGG
RTECS number
  • GG3100000 (anhydrous)
    GG3200000 (heptahydrate)
UNII
  • InChI=1S/Co.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2 checkY
    Key: KTVIXTQDYHMGHF-UHFFFAOYSA-L checkY
  • InChI=1/Co.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2
    Key: KTVIXTQDYHMGHF-NUQVWONBAJ
  • anhydrous: [Co+2].[O-]S([O-])(=O)=O
  • hexahydrate: [OH2+][Co-4]([OH2+])([OH2+])([OH2+])([OH2+])[OH2+].[O-]S(=O)(=O)[O-]
  • heptahydrate: [OH2+][Co-4]([OH2+])([OH2+])([OH2+])([OH2+])[OH2+].[O-]S(=O)(=O)[O-].O
Properties
CoSO4·(H2O)n (n=0,1,6,7)
Molar mass 154.996 g/mol (anhydrous)
173.01 g/mol (monohydrate)
263.08 g/mol (hexahydrate)
281.103 g/mol (heptahydrate)
Appearance reddish crystalline (anhydrous, monohydrate)
pink salt (hexahydrate)
Odor odorless (heptahydrate)
Density 3.71 g/cm3 (anhydrous)
3.075 g/cm3 (monohydrate)
2.019 g/cm3 (hexahydrate)
1.948 g/cm3 (heptahydrate)
Melting point 735 °C (1,355 °F; 1,008 K)
anhydrous:
36.2 g/100 mL (20 °C)
38.3 g/100 mL (25 °C)
84 g/100 mL (100 °C)
heptahydrate:
60.4 g/100 mL (3 °C)
67 g/100 mL (70 °C)
Solubility anhydrous:
1.04 g/100 mL (methanol, 18 °C)
insoluble in ammonia
heptahydrate:
54.5 g/100 mL (methanol, 18 °C)
+10,000·10−6 cm3/mol
1.639 (monohydrate)
1.540 (hexahydrate)
1.483 (heptahydrate)
Structure
orthorhombic (anhydrous)
monoclinic (monohydrate, heptahydrate)
Hazards
GHS labelling:
GHS07: Exclamation markGHS08: Health hazardGHS09: Environmental hazard
Danger
H302, H317, H334, H341, H350, H360, H410
P201, P202, P261, P264, P270, P272, P273, P280, P281, P285, P301+P312, P302+P352, P304+P341, P308+P313, P321, P330, P333+P313, P342+P311, P363, P391, P405, P501
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
0
0
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
424 mg/kg (oral, rat)
Safety data sheet (SDS) ICSC 1396 (heptahydrate)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Cobalt(II) sulfate
Cobalt(II) sulfate heptahydrate

Cobalt(II) sulfate is any of the inorganic compounds with the formula CoSO4(H2O)x. Usually cobalt sulfate refers to the hexa- or heptahydrates CoSO4.6H2O or CoSO4.7H2O, respectively.[1] The heptahydrate is a red solid that is soluble in water and methanol. Since cobalt(II) has an odd number of electrons, its salts are paramagnetic.

  1. ^ Cite error: The named reference Ullmann was invoked but never defined (see the help page).

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