Deuterium

Deuterium, hydrogen-2, D, 2H
Deuterium glowing in a gas discharge tube
General
Symbol2H
NamesDeuterium, hydrogen-2, D, 2H, H-2,
hydrogen-2, D, 2H
Protons (Z)1
Neutrons (N)1
Nuclide data
Natural abundance0.0156% (Earth)[1]
Half-life (t1/2)stable
Isotope mass2.01410177811[2] Da
Spin1+
Excess energy13135.720±0.001 keV
Binding energy2224.57±0.20 keV
Isotopes of hydrogen
Complete table of nuclides

Deuterium (hydrogen-2, symbol 2H or D, also known as heavy hydrogen) is one of two stable isotopes of hydrogen; the other is protium, or hydrogen-1, 1H. The deuterium nucleus (deuteron) contains one proton and one neutron, whereas the far more common 1H has no neutrons.

The name deuterium comes from Greek deuteros, meaning "second".[3][4] American chemist Harold Urey discovered deuterium in 1931. Urey and others produced samples of heavy water in which the 2H had been highly concentrated. The discovery of deuterium won Urey a Nobel Prize in 1934.

Nearly all deuterium found in nature was synthesized in the Big Bang 13.8 billion years ago, forming the primordial ratio of 2H to 1H (≈26 deuterium nuclei per 106 hydrogen nuclei). Deuterium is subsequently produced by the slow stellar proton–proton chain, but rapidly destroyed by exothermic fusion reactions. The deuterium-deuterium reaction has the second-lowest energy threshold, and is the most astrophysically accessible, occurring in both stars and brown dwarfs.

The gas giant planets display the primordial ratio of deuterium. Comets show an elevated ratio similar to Earth's oceans (156 deuterium nuclei per 106 hydrogen nuclei). This reinforces theories that much of Earth's ocean water is of cometary origin.[5][6] The deuterium ratio of comet 67P/Churyumov–Gerasimenko, as measured by the Rosetta space probe, is about three times that of Earth water. This figure is the highest yet measured in a comet, thus deuterium ratios continue to be an active topic of research in both astronomy and climatology.[7]

Deuterium is used in most nuclear weapons, many fusion power experiments, and as the most effective neutron moderator, primarily in heavy water nuclear reactors. It is also used as an isotopic label, in biogeochemistry, NMR spectroscopy, and deuterated drugs.

  1. ^ Hagemann R, Nief G, Roth E (1970). "Absolute isotopic scale for deuterium analysis of natural waters. Absolute D/H ratio for SMOW 1". Tellus. 22 (6): 712–715. Bibcode:1970Tell...22..712H. doi:10.1111/j.2153-3490.1970.tb00540.x.
  2. ^ Wang, M.; Audi, G.; Kondev, F. G.; Huang, W. J.; Naimi, S.; Xu, X. (2017). "The AME2016 atomic mass evaluation (II). Tables, graphs, and references" (PDF). Chinese Physics C. 41 (3): 030003-1 – 030003-442. doi:10.1088/1674-1137/41/3/030003.
  3. ^ Harold Urey; G. M. Murphy; F. G. Brickwedde (1933). "A Name and Symbol for H2". Journal of Chemical Physics. 1 (7): 512–513. doi:10.1063/1.1749326.
  4. ^ O'Leary D (February 2012). "The deeds to deuterium". Nature Chemistry. 4 (3): 236. Bibcode:2012NatCh...4..236O. doi:10.1038/nchem.1273. PMID 22354440.
  5. ^ Hartogh P, Lis DC, Bockelée-Morvan D, de Val-Borro M, Biver N, Küppers M, et al. (October 2011). "Ocean-like water in the Jupiter-family comet 103P/Hartley 2". Nature. 478 (7368): 218–220. Bibcode:2011Natur.478..218H. doi:10.1038/nature10519. PMID 21976024. S2CID 3139621.
  6. ^ Hersant F, Gautier D, Hure JM (2001). "A two-dimensional model for the primordial nebula constrained by D/H measurements in the Solar system: Implications for the formation of giant planets". The Astrophysical Journal. 554 (1): 391–407. Bibcode:2001ApJ...554..391H. doi:10.1086/321355. — see fig. 7. for a review of D/H ratios in various astronomical objects
  7. ^ Altwegg K, Balsiger H, Bar-Nun A, Berthelier JJ, Bieler A, Bochsler P, et al. (January 2015). "Cometary science. 67P/Churyumov–Gerasimenko, a Jupiter family comet with a high D/H ratio" (PDF). Science. 347 (6220): 1261952. Bibcode:2015Sci...347A.387A. doi:10.1126/science.1261952. PMID 25501976. S2CID 206563296.

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