Electrode potential

In electrochemistry, electrode potential is the voltage of a galvanic cell built from a standard reference electrode and another electrode to be characterized.^[1] By convention, the reference electrode is the standard hydrogen electrode (SHE). It is defined to have a potential of zero volts. It may also be defined as the potential difference between the charged metallic rods and salt solution.

The electrode potential has its origin in the potential difference developed at the interface between the electrode and the electrolyte. It is common, for instance, to speak of the electrode potential of the M⁺/M redox couple.