Lanthanite

Lanthanite-(La), Lanthanite-(Nd), Lanthanite-(Ce)
Lanthanite-(Nd) from Mitsukoshi, Hizen-cho, Karatsu City, Saga Prefecture, Japan.
General
CategoryCarbonate minerals
Formula
(repeating unit)
(REE)2(CO3)3·8(H2O)
IMA symbolLtn[1]
Strunz classification5.CC.25
Dana classification(La): 15.04.02.01
(Nd): 15.04.02.02
(Ce): 15.04.02.03
Crystal systemOrthorhombic
Crystal classDipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space groupPbnb
Unit cella = 9.476(4)-9.483(6)
b = 16.940(8)-16.938(11)
c = 8.942(4)-8.965(3) [Å], Z = 4
Identification
ColorPale pink to purple
Crystal habitPlaty
TwinningCommon on {101}
CleavageMicaceous, perfect on {101}
FractureUneven
TenacitySectile
Mohs scale hardness2.5
LusterVitreous to pearly
StreakWhite
Density2.78-2.84 (measured), 2.79-2.816 (calculated)
Optical propertiesBiaxial (-)
2V angle58-61° (measured), 60-63.5° (calculated)
References[2]

Lanthanites are a group of isostructural rare earth element (REE) carbonate minerals. This group comprises the minerals lanthanite-(La),[3][4] lanthanite-(Ce),[5] and lanthanite-(Nd).[6] This mineral group has the general chemical formula of (REE)2(CO3)3·8(H2O). Lanthanites include La, Ce, and Nd as major elements and often contain subordinate amounts of other REEs including praseodymium (Pr), samarium (Sm), europium (Eu) and dysprosium (Dy).[7] The lanthanite crystal structure consists of layers of 10-fold coordinated REE-oxygen (O) polyhedra and carbonate (CO32−) groups connected by hydrogen bonds to interlayer water molecules, forming a highly hydrated structure.[8]

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Lanthanite on Mindat
  3. ^ Haidinger W (1845) Zweite Klasse: Geogenide. II. Ordnung. Baryte. III. Cerebaryt. Lanthanit., in Handbuch der Bestimmenden Mineralogie, Bei Braumüller and Seidel (Wien) 499-506.
  4. ^ Nickel E H, Mandarino J A (1987) Procedures involving the IMA Commission on New Minerals and Mineral Names and guidelines on mineral nomenclature, American Mineralogist 72, 1031-1042.
  5. ^ Bevins R E, Rowbotham G, Stephens F S, Turgoose S, Williams P A (1985) Lanthanite-(Ce), (Ce,La,Nd)2(CO3)3·8H2O, a new mineral from Wales, U.K.. American Mineralogist 70, 411-413.
  6. ^ Roberts A C, Chao G Y, Cesbron F (1980) Lanthanite-(Nd), a new mineral from Curitiba, Parana, Brazil, Geological Survey of Canada Paper 80-1C, 141-142.
  7. ^ The Canadian Mineralogist 45 (2007) 1389-1396.
  8. ^ Morrison, S. M., Andrade, M. B., Wenz, M. D., Domanik, K. J., & Downs, R. T. (2013). Lanthanite-(Nd), Nd2 (CO3) 3.8 H2O. Acta Crystallographica Section E: Structure Reports Online, 69(3), i15-i16. doi:10.1107/S1600536813003164

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