Lithium perchlorate

Lithium perchlorate
	; __ Li+ __ Cl7+ __ O2− ; Unit cell of lithium perchlorate.
Names
	IUPAC name Lithium perchlorate
	Other names Perchloric acid, lithium salt; Lithium Cloricum
Identifiers
CAS Number	7791-03-9 ;
3D model (JSmol)	Interactive image;
ChemSpider	133514 ;
ECHA InfoCard	100.029.307
PubChem CID	23665649;
UNII	Q86SE98C9C ;
CompTox Dashboard (EPA)	DTXSID40872829 ;
	InChI InChI=1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1 Key: MHCFAGZWMAWTNR-UHFFFAOYSA-M ; InChI=1/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1 Key: MHCFAGZWMAWTNR-REWHXWOFAR;
	SMILES [Li+].[O-]Cl(=O)(=O)=O;
Properties
Chemical formula	LiClO; 4
Molar mass	106.39 g/mol (anhydrous); 160.44 g/mol (trihydrate);
Appearance	White crystals
Odor	Odorless
Density	2.42 g/cm3
Melting point	236 °C (457 °F; 509 K)
Boiling point	430 °C (806 °F; 703 K) ; decomposes from 400 °C
Solubility in water	42.7 g/100 mL (0 °C); 49 g/100 mL (10 °C); 59.8 g/100 mL (25 °C); 71.8 g/100 mL (40 °C); 119.5 g/100 mL (80 °C); 300 g/100 g (120 °C);
Solubility	Soluble in alcohols, ethyl acetate
Solubility in acetone	137 g/100 g
Solubility in alcohols	182 g/100 g (CH3OH); 152 g/100 g (C2H5OH); 105 g/100 g (C3H7OH); 79.3 g/100 g (n-C4H9OH); 58 g/100 g (i-C4H9OH;
Solubility in ethyl acetate	95.2 g/100 g
Solubility in ethyl ether	113.7 g/100 g
Structure
Space group	Pnma, No. 62
Lattice constant	a = 865.7(1) pm, b = 691.29(9) pm, c = 483.23(6) pm
Formula units (Z)	4 formula per cell
Coordination geometry	tetrahedral at Cl
Thermochemistry
Heat capacity (C)	105 J/mol·K
Std molar; entropy (S⦵298)	125.5 J/mol·K
Std enthalpy of; formation (ΔfH⦵298)	−380.99 kJ/mol
Gibbs free energy (ΔfG⦵)	−254 kJ/mol
Hazards
	Occupational safety and health (OHS/OSH):
Main hazards	Oxidizer, irritant
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H272, H315, H319, H335
Precautionary statements	P220, P261, P305+P351+P338
NFPA 704 (fire diamond)	2 0 0 OX
Safety data sheet (SDS)	MSDS
Related compounds
Other anions	Lithium chloride; Lithium hypochlorite; Lithium chlorate
Other cations	Sodium perchlorate; Potassium perchlorate; Rubidium perchlorate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Lithium perchlorate is the inorganic compound with the formula LiClO₄. This white or colourless crystalline salt is noteworthy for its high solubility in many solvents. It exists both in anhydrous form and as a trihydrate.

^ ^a ^b ^c ^d ^e ^f ^g "Lithium perchlorate". chemister.ru.
^ ^a ^b "Lithium Perchlorate". AMCP 706-187 Military Pyrotechnics - Properties of Materials. US Army Materiel Command. October 1963. pp. 181–182.
^ Wickleder, Mathias S. (2003). "Crystal Structure of LiClO4". Zeitschrift für Anorganische und Allgemeine Chemie. 629 (9): 1466–1468. doi:10.1002/zaac.200300114.
^ ^a ^b ^c Sigma-Aldrich Co., Lithium perchlorate. Retrieved on 2014-05-09.

[chemister-1] ^ ^a ^b ^c ^d ^e ^f ^g "Lithium perchlorate". chemister.ru.

[AMCP-2] "Lithium Perchlorate". AMCP 706-187 Military Pyrotechnics - Properties of Materials. US Army Materiel Command. October 1963. pp. 181–182.

[3] Wickleder, Mathias S. (2003). "Crystal Structure of LiClO4". Zeitschrift für Anorganische und Allgemeine Chemie. 629 (9): 1466–1468. doi:10.1002/zaac.200300114.

[sigma-4] Sigma-Aldrich Co., Lithium perchlorate. Retrieved on 2014-05-09.

[1]

[2]

[3]

[4]

Names

__ Li⁺ __ Cl⁷⁺ __ O²⁻ Unit cell of lithium perchlorate.
IUPAC name Lithium perchlorate
Other names Perchloric acid, lithium salt; Lithium Cloricum
Identifiers
CAS Number	7791-03-9^Y
3D model (JSmol)	Interactive image
ChemSpider	133514^Y
ECHA InfoCard	100.029.307
PubChem CID	23665649
UNII	Q86SE98C9C^N
CompTox Dashboard (EPA)	DTXSID40872829
InChI InChI=1S/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1^Y Key: MHCFAGZWMAWTNR-UHFFFAOYSA-M^Y InChI=1/ClHO4.Li/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1 Key: MHCFAGZWMAWTNR-REWHXWOFAR
SMILES [Li+].[O-]Cl(=O)(=O)=O
Properties
Chemical formula	LiClO ₄
Molar mass	106.39 g/mol (anhydrous) 160.44 g/mol (trihydrate)
Appearance	White crystals
Odor	Odorless
Density	2.42 g/cm³
Melting point	236 °C (457 °F; 509 K)
Boiling point	430 °C (806 °F; 703 K) decomposes from 400 °C
Solubility in water	42.7 g/100 mL (0 °C) 49 g/100 mL (10 °C) 59.8 g/100 mL (25 °C) 71.8 g/100 mL (40 °C) 119.5 g/100 mL (80 °C) 300 g/100 g (120 °C)^[1]
Solubility	Soluble in alcohols, ethyl acetate^[1]
Solubility in acetone	137 g/100 g^[1]
Solubility in alcohols	182 g/100 g (CH₃OH) 152 g/100 g (C₂H₅OH) 105 g/100 g (C₃H₇OH) 79.3 g/100 g (n-C₄H₉OH) 58 g/100 g (i-C₄H₉OH^[1]
Solubility in ethyl acetate	95.2 g/100 g^[2]
Solubility in ethyl ether	113.7 g/100 g^[2]
Structure
Space group	Pnma, No. 62
Lattice constant	a = 865.7(1) pm, b = 691.29(9) pm, c = 483.23(6) pm^[3]
Formula units (Z)	4 formula per cell
Coordination geometry	tetrahedral at Cl
Thermochemistry
Heat capacity (C)	105 J/mol·K^[1]
Std molar entropy (S^⦵₂₉₈)	125.5 J/mol·K^[1]
Std enthalpy of formation (Δ_fH^⦵₂₉₈)	−380.99 kJ/mol
Gibbs free energy (Δ_fG^⦵)	−254 kJ/mol^[1]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards	Oxidizer, irritant
GHS labelling:
Pictograms	^[4]
Signal word	Danger
Hazard statements	H272, H315, H319, H335^[4]
Precautionary statements	P220, P261, P305+P351+P338^[4]
NFPA 704 (fire diamond)	2 0 0 OX
Safety data sheet (SDS)	MSDS
Related compounds
Other anions	Lithium chloride Lithium hypochlorite Lithium chlorate
Other cations	Sodium perchlorate Potassium perchlorate Rubidium perchlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is ^YN ?) Infobox references