Methyl acrylate

Methyl acrylate
Skeletal formula of methyl Acrylate
Ball-and-stick model of the methyl acrylate molecule
Names
Preferred IUPAC name
Methyl prop-2-enoate[1]
Other names
Methyl acrylate
Methyl propenoate
Methoxycarbonylethylene
Curithane 103[1]
Identifiers
3D model (JSmol)
ChEMBL
ChemSpider
ECHA InfoCard 100.002.274 Edit this at Wikidata
KEGG
UNII
  • InChI=1S/C4H6O2/c1-3-4(5)6-2/h3H,1H2,2H3 checkY
    Key: BAPJBEWLBFYGME-UHFFFAOYSA-N checkY
  • C=CC(OC)=O
Properties
C4H6O2
Molar mass 86.090 g·mol−1
Appearance Colorless liquid
Odor Acrid[2]
Density 0.95 g/cm3[3]
Melting point −74 °C (−101 °F; 199 K)[3]
Boiling point 80 °C (176 °F; 353 K)[3]
5 g/100 mL
Vapor pressure 65 mmHg (20°C)[2]
Viscosity
  • 0.391 mPa·s at 35 °C[4]
  • 0.333 mPa·s at 45 °C[4]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Harmful (Xn); Highly flammable (F+)
Flash point −3 °C (27 °F; 270 K)[3]
Explosive limits 2.8–25%[2]
Lethal dose or concentration (LD, LC):
3575 ppm (mouse)
1350 ppm (rat, 4 hr)
1000 ppm (rat, 4 hr)
2522 ppm (rabbit, 1 hr)[5]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 10 ppm (35 mg/m3) [skin][2]
REL (Recommended)
TWA 10 ppm (35 mg/m3) [skin][2]
IDLH (Immediate danger)
250 ppm[2]
Safety data sheet (SDS) Oxford MSDS
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Methyl acrylate is an organic compound, more accurately the methyl ester of acrylic acid. It is a colourless liquid with a characteristic acrid odor. It is mainly produced to make acrylate fiber, which is used to weave synthetic carpets.[6] It is also a reagent in the synthesis of various pharmaceutical intermediates. Owing to the tendency of methyl acrylate to polymerize, samples typically contain an inhibitor such as hydroquinone.

  1. ^ a b "methyl acrylate - Compound Summary". PubChem. Retrieved June 30, 2012.
  2. ^ a b c d e f NIOSH Pocket Guide to Chemical Hazards. "#0394". National Institute for Occupational Safety and Health (NIOSH).
  3. ^ a b c d Record in the GESTIS Substance Database of the Institute for Occupational Safety and Health
  4. ^ a b George, John; Sastry, Nandhibatla V.; Patel, Sunil R.; Valand, Mahendra K. (2002). "Densities, Viscosities, Speeds of Sound, and Relative Permittivities for Methyl Acrylate + 1-Alcohols (C1−C6) atT= (308.15 and 318.15) K". Journal of Chemical & Engineering Data. 47 (2). American Chemical Society (ACS): 262–269. doi:10.1021/je010268l. ISSN 0021-9568.
  5. ^ "Methyl acrylate". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
  6. ^ Takashi Ohara; Takahisa Sato; Noboru Shimizu; Günter Prescher Helmut Schwind; Otto Weiberg; Klaus Marten; Helmut Greim (2003). "Acrylic Acid and Derivatives". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a01_161.pub2. ISBN 3-527-30673-0.

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