Nathaniel Smith (1762–1822) was a US Representative from Connecticut.
Nathaniel Smith may also refer to:
- Nathaniel Smith (MP) (1730–1794), MP for Rochester and Pontefract
- Nathaniel Smith (Tioga County, NY) in 55th New York State Legislature
- Nathaniel Benedict Smith (1795–1881), Connecticut legislator, son of the US Representative
- Nathaniel Cannon Smith (1866–1943), American painter and architect
- Nathaniel Clark Smith (1877–1935), African-American musician, composer and music educator
- Nathaniel Smith (Australian politician), member of the New South Wales Legislative Assembly
- Nathaniel W. Smith, lieutenant governor of Rhode Island
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