Nitrosyl perchlorate

Nitrosyl perchlorate
Structure of nitrosyl perchlorate
Names
IUPAC names
Perchloryl nitrite
Nitrosonium perchlorate
Other names
Nitrosyl perchlorate
Perchloric nitrous anhydride
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/ClNO5/c3-1(4,5)7-2-6
    Key: ONKVXKHGDFDPFZ-UHFFFAOYSA-N
  • N(=O)OCl(=O)(=O)=O
Properties
NOClO4
Molar mass 129.46 g/mol
Appearance white solid
Density 2.169 g/cm3[1]
Melting point 100 °C (212 °F; 373 K) (decomposes)
Reacts
Structure
Rhombic[1]
Thermochemistry
-154.0 kJ/mol[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Nitrosyl perchlorate is the inorganic compound with the formula NO(ClO4). A hygroscopic white solid, it is the salt of the nitrosonium cation with the perchlorate anion. It is an oxidant and strong electrophile, but has fallen out of use with the availability of the closely related salt nitrosonium tetrafluoroborate NO(BF4).

  1. ^ a b c Cite error: The named reference patr2700 was invoked but never defined (see the help page).

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