Polytetrafluoroethylene

Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene, and has numerous applications because it is chemically inert. The commonly known brand name of PTFE-based composition is Teflon by Chemours,[1] a spin-off from DuPont, which originally discovered the compound in 1938.[1]

Polytetrafluoroethylene
Names
IUPAC name
Poly(1,1,2,2-tetrafluoroethylene)[2]
Other names
Fluon, Poly(tetrafluoroethene), Poly(difluoromethylene), Poly(tetrafluoroethylene), teflon
Identifiers
Abbreviations PTFE
ChEBI
ChemSpider
  • None
ECHA InfoCard 100.120.367 Edit this at Wikidata
KEGG
UNII
Properties
(C2F4)n
Density 2200 kg/m3
Melting point 327 °C
Electrical resistivity 1018 Ω·cm[a]
Thermal conductivity 0.25 W/(m·K)
Hazards
NFPA 704 (fire diamond)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Polytetrafluoroethylene is a fluorocarbon solid, as it is a high-molecular-weight polymer consisting wholly of carbon and fluorine. PTFE is hydrophobic: neither water nor water-containing substances wet PTFE, as fluorocarbons exhibit only small London dispersion forces due to the low electric polarizability of fluorine. PTFE has one of the lowest coefficients of friction of any solid.

Polytetrafluoroethylene is used as a non-stick coating for pans and other cookware. It is non-reactive, partly because of the strength of carbon–fluorine bonds, so it is often used in containers and pipework for reactive and corrosive chemicals. Where used as a lubricant, PTFE reduces friction, wear, and energy consumption of machinery. It is used as a graft material in surgery and as a coating on catheters.

PTFE is one of the best-known and widely applied PFAS commonly described as persistent organic pollutants or "forever chemicals". Only since the start of the 21st century has the environmental impact and toxicity to human and mammalian life been studied in depth. For decades, DuPont used perfluorooctanoic acid (PFOA, or C8) during production of PTFE, later discontinuing its use due to ecotoxicological and health issues that led to legal actions. Dupont's spin-off Chemours today manufactures PTFE using an alternative chemical it calls GenX, another PFAS.

  1. ^ a b "The History of Teflon Fluoropolymers". Teflon.com. Retrieved 3 February 2021.
  2. ^ "poly(tetrafluoroethylene) (CHEBI:53251)". ebi.ac.uk. Retrieved 12 July 2012.
  3. ^ "PTFE". Microwaves101. Archived from the original on 16 July 2014. Retrieved 16 February 2012.


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