Redox

Redox (/ˈrɛdɒks/ RED-oks, /ˈriːdɒks/ REE-doks, reduction–oxidation^[2] or oxidation–reduction^[3]: 150) is a type of chemical reaction in which the oxidation states of a reactant change^[4] and that reduction and oxidation occur at the same time in a reaction. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state.

There are two classes of redox reactions:

• Electron-transfer – Only one (usually) electron flows from the atom, ion or molecule being oxidized to the atom, ion, or molecule that is reduced. This type of redox reaction is often discussed in terms of redox couples and electrode potentials.
• Atom transfer – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function.^[5] In hydrogenation, bonds like C=C are reduced by transfer of hydrogen atoms.