Tantalum(V) bromide

Tantalum(V) bromide
Tantalum(V) bromide
Names
Other names
tantalum pentabromide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.276 Edit this at Wikidata
EC Number
  • 236-618-4
  • Key: GCPVYIPZZUPXPB-UHFFFAOYSA-I
  • InChI=1S/5BrH.Ta/h5*1H;/q;;;;;+5/p-5
  • Br[Ta](Br)(Br)(Br)Br
Properties
Ta2Br10
Molar mass 580.468 g/mol
Appearance yellow solid
Density 4.99 g/cm3, solid
Melting point 265 °C (509 °F; 538 K)
Boiling point 349 °C (660 °F; 622 K)
hydrolysis
Hazards
GHS labelling:[1]
GHS05: CorrosiveGHS06: ToxicGHS07: Exclamation mark
Danger
H302, H312, H314, H332
P260, P261, P264, P270, P271, P280, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P310, P311, P312, P321, P322, P330, P361, P363, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tantalum(V) bromide is the inorganic compound with the formula Ta2Br10. Its name comes from the compound's empirical formula, TaBr5.[2] It is a diamagnetic, orange solid that hydrolyses readily. The compound adopts an edge-shared bioctahedral structure, which means that two TaBr5 units are joined by a pair of bromide bridges. There is no bond between the Ta centres.[3] Niobium(V) chloride, niobium(V) bromide, niobium(V) iodide, tantalum(V) chloride, and tantalum(V) iodide all share this structural motif.

  1. ^ "Tantalum(V) bromide". pubchem.ncbi.nlm.nih.gov. Retrieved 16 December 2021.
  2. ^ Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. ISBN 0-7506-3365-4.
  3. ^ Habermehl, Katja; Pantenburg, Ingo; Meyer, Gerd (2010). "Redetermination of tantalum pentabromide, (TaBr5)2". Acta Crystallographica Section E. 66 (9): i67. doi:10.1107/S1600536810032538. PMC 3007875. PMID 21588474.

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