Telluric acid

Telluric acid
Skeletal formula of ortho-telluric acid
Ball-and-stick model of ortho-telluric acid
Names
IUPAC name
Hexahydroxidotellurium
Other names
  • Orthotelluric acid
  • Hexahydroxytellurium
  • Hexahydroxy-λ6-tellane
  • Tellurium hexahydroxide
  • Tellurium(VI) hydroxide
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.029.334 Edit this at Wikidata
UNII
  • InChI=1S/H2O4Te/c1-5(2,3)4/h(H2,1,2,3,4) checkY
    Key: XHGGEBRKUWZHEK-UHFFFAOYSA-N checkY
  • InChI=1/H2O4Te/c1-5(2,3)4/h(H2,1,2,3,4)
    Key: XHGGEBRKUWZHEK-UHFFFAOYAT
  • O[Te](O)(O)(O)(O)O
Properties
Te(OH)6
Molar mass 229.64 g·mol−1
Appearance White monoclinic crystals
Density 3.07 g/cm3
Melting point 136 °C (277 °F; 409 K)
50.1 g/(100 ml) at 30 °C[1]
Acidity (pKa) 7.5, 11, 14[2]
Conjugate base Tellurate
Structure
octahedral
0 D
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
corrosive
Related compounds
Other anions
Hydrotelluric acid
Tellurous acid
Hydrogen telluride
Related compounds
Teflic acid
Sulfuric acid
Selenic acid
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)

Telluric acid, or more accurately orthotelluric acid, is a chemical compound with the formula Te(OH)6, often written as H6TeO6. It is a white crystalline solid made up of octahedral Te(OH)6 molecules which persist in aqueous solution.[3] In the solid state, there are two forms, rhombohedral and monoclinic, and both contain octahedral Te(OH)6 molecules,[4] containing one hexavalent tellurium (Te) atom in the +6 oxidation state, attached to six hydroxyl (–OH) groups, thus, it can be called tellurium(VI) hydroxide. Telluric acid is a weak acid which is dibasic, forming tellurate salts with strong bases and hydrogen tellurate salts with weaker bases or upon hydrolysis of tellurates in water.[4][5] It is used as tellurium-source in the synthesis of oxidation catalysts.

  1. ^ Lide, David R. (1998), Handbook of Chemistry and Physics (87 ed.), Boca Raton, Florida: CRC Press, ISBN 0-8493-0594-2
  2. ^ Perrin, D. D., ed. (1982) [1969]. Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution. IUPAC Chemical Data (2nd ed.). Oxford: Pergamon (published 1984). Entry 219. ISBN 0-08-029214-3. LCCN 82-16524.
  3. ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
  4. ^ a b Cotton, F. Albert; Wilkinson, Geoffrey; Murillo, Carlos A.; Bochmann, Manfred (1999), Advanced Inorganic Chemistry (6th ed.), New York: Wiley-Interscience, ISBN 0-471-19957-5
  5. ^ Holleman, A. F.; Wiberg, E. "Inorganic Chemistry" Academic Press: San Diego, 2001. ISBN 0-12-352651-5.

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