Trichlorofluoromethane

Trichlorofluoromethane
Names
Preferred IUPAC name
Trichloro(fluoro)methane
Other names
Trichlorofluoromethane
Fluorotrichloromethane
Fluorochloroform
Freon 11
CFC 11
R 11
Arcton 9
Freon 11A
Freon 11B
Freon HE
Freon MF
Identifiers
3D model (JSmol)
ChEBI
ChEMBL
ChemSpider
ECHA InfoCard 100.000.812 Edit this at Wikidata
EC Number
  • 200-892-3
RTECS number
  • PB6125000
UNII
  • InChI=1S/CCl3F/c2-1(3,4)5 checkY
    Key: CYRMSUTZVYGINF-UHFFFAOYSA-N checkY
  • InChI=1/CCl3F/c2-1(3,4)5
  • C(F)(Cl)(Cl)Cl
  • ClC(Cl)(Cl)F
Properties
CCl3F
Molar mass 137.36 g·mol−1
Appearance Colorless liquid/gas
Odor nearly odorless[1]
Density 1.494 g/cm3
Melting point −110.48 °C (−166.86 °F; 162.67 K)
Boiling point 23.77 °C (74.79 °F; 296.92 K)
1.1 g/L (at 20 °C)
log P 2.53
Vapor pressure 89 kPa at 20 °C
131 kPa at 30 °C
Thermal conductivity 0.0079 W m−1 K−1 (gas at 300 K, ignoring pressure dependence)[2][verification needed]
Hazards
GHS labelling:[4]
GHS07: Exclamation mark
Warning
H420
P502
Flash point Non-flammable
Lethal dose or concentration (LD, LC):
26,200 ppm (rat, 4 hr)
100,000 ppm (rat, 20 min)
100,000 ppm (rat, 2 hr)[3]
NIOSH (US health exposure limits):
PEL (Permissible)
TWA 1000 ppm (5600 mg/m3)[1]
REL (Recommended)
C 1000 ppm (5600 mg/m3)[1]
IDLH (Immediate danger)
2000 ppm[1]
Safety data sheet (SDS) ICSC 0047
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Trichlorofluoromethane, also called freon-11, CFC-11, or R-11, is a chlorofluorocarbon (CFC). It is a colorless, faintly ethereal, and sweetish-smelling liquid that boils around room temperature.[5] CFC-11 is a Class 1 ozone-depleting substance which damages Earth's protective stratospheric ozone layer.[6] Also R-11 is not flammable at ambient temperature and pressure but it can become very combustible if heated and ignited by a strong ignition source.

  1. ^ a b c d NIOSH Pocket Guide to Chemical Hazards. "#0290". National Institute for Occupational Safety and Health (NIOSH).
  2. ^ Touloukian, Y.S., Liley, P.E., and Saxena, S.C. Thermophysical properties of matter - the TPRC data series. Volume 3. Thermal conductivity - nonmetallic liquids and gases. Data book. 1970.
  3. ^ "Fluorotrichloromethane". Immediately Dangerous to Life or Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH).
  4. ^ Record in the GESTIS Substance Database of the Institute for Occupational Safety and Health
  5. ^ Siegemund, Günter; Schwertfeger, Werner; Feiring, Andrew; Smart, Bruce; Behr, Fred; Vogel, Herward; McKusick, Blaine (2002). "Fluorine Compounds, Organic". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a11_349. ISBN 978-3527306732.
  6. ^ "International Treaties and Cooperation about the Protection of the Stratospheric Ozone Layer". U.S. Environmental Protection Agency. 15 July 2015. Retrieved 2021-02-14.

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