Tris(acetylacetonato)cobalt(III)

Tris(acetylacetonato)cobalt(III)
Names
Other names
Cobalt(III) acetylacetonate, tris(acac) cobalt
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.040.464 Edit this at Wikidata
EC Number
  • 244-527-6
  • InChI=1S/3C5H8O2.Co/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3+;
    Key: RHCQEPWEBDOALW-MUCWUPSWSA-K
  • C/C(=C\C(=O)C)/[O-].C/C(=C\C(=O)C)/[O-].C/C(=C\C(=O)C)/[O-].[Co+3]
Properties
C15H21CoO6
Molar mass 356.260 g·mol−1
Appearance green solid
Density 1.41 g/cm3
Melting point 213 °C (415 °F; 486 K)
Hazards
GHS labelling:
GHS07: Exclamation markGHS08: Health hazard
Danger
H302, H317, H334
P261, P264, P270, P272, P280, P285, P301+P312, P302+P352, P304+P341, P321, P330, P333+P313, P342+P311, P363, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Tris(acetylacetonato)cobalt(III) is the coordination complex with the formula Co(C5H7O2)3. Often abbreviated Co(acac)3, it is a green, diamagnetic solid that is soluble in organic solvents, but not in water. Owing to its solubility in organic solvents, tris(acetylacetonato)cobalt(III) is used to produce homogeneous catalysts by reduction.[1]

  1. ^ Mayo, Peter D.; Tam, William (2002). "Tris(acetoacetonyl)cobalt". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rn00084. ISBN 0-471-93623-5.

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