Uranium hexachloride

Uranium hexachloride
Names
IUPAC name
Uranium(VI) chloride
Other names
Uranium hexachloride
Peruranic chloride
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/6ClH.U/h6*1H;/p-6
    Key: XFCORTPUZRSUIZ-UHFFFAOYSA-H
  • [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[U]
Properties
UCl6
Molar mass 450.745 g/mol
Appearance dark green crystalline solid
Density 3.6 g/cm3
Melting point 177 °C (351 °F; 450 K)
Related compounds
Other anions
Uranium hexafluoride
Other cations
Tungsten hexachloride
Related uranium chlorides
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Uranium hexachloride is the inorganic compound with the formula UCl6. It features uranium in the +6 oxidation state.[1] UCl6 hydrolyzes readily but is stable under inert atmosphere. It is soluble in carbon tetrachloride (CCl4). It is a multi-luminescent dark green or black solid with a vapor pressure between 1-3 mmHg at 373.15 K.[2]

  1. ^ O'Donnell, T. A.; Wilson, P. W. (1976). "Uranium Hexachloride: (Hexachlorouranium )". Inorganic Syntheses. 16: 143. doi:10.1002/9780470132470.ch39.
  2. ^ Van Dyke, R. E.; Evers, E. C. (1955). "Preparation of Uranium Hexachloride". Google Patents: 2.

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