Van 't Hoff equation

The Van 't Hoff equation relates the change in the equilibrium constant, Keq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, ΔrH, for the process. The subscript means "reaction" and the superscript means "standard". It was proposed by Dutch chemist Jacobus Henricus van 't Hoff in 1884 in his book Études de Dynamique chimique (Studies in Dynamic Chemistry).[1]

The Van 't Hoff equation has been widely utilized to explore the changes in state functions in a thermodynamic system. The Van 't Hoff plot, which is derived from this equation, is especially effective in estimating the change in enthalpy and entropy of a chemical reaction.

  1. ^ Biography on Nobel prize website. Nobelprize.org (1 March 1911). Retrieved on 2013-11-08.

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