Ionization energy

Ionization energy and Atomic number

Ionization energy is the energy needed to remove the most loosely attached electron from an atom. The atom is not connected to any other atoms. The chemical elements to the left of the periodic table have a much lower ionization energy. The ones to the right have a much higher ionization energy. The chemical elements down the periodic table have a much lower ionization energy (due to electrons being farther away from the atom with increasing atomic radius). The ionization energy increases as each electron is removed.

Ionization energies are dependent upon the atomic radius. Since going from right to left on the periodic table, the atomic radius increases, and the ionization energy increases from left to right in the periods and up the groups. Exceptions to this trend is observed for alkaline earth metals (group 2) and nitrogen group elements (group 15). Typically, group 2 elements have ionization energy greater than group 13 elements and group 15 elements have greater ionization energy than group 16 elements. Groups 2 and 15 have completely and half-filled electronic configuration respectively, thus, it requires more energy to remove an electron from completely filled orbitals than incompletely filled orbitals.

Alkali metals (IA group) have small ionization energies, especially when compared to halogens or VII A group. In addition to the radius (distance between nucleus and the electrons in outermost orbital), the number of electrons between the nucleus and the electron(s) you're looking at in the outermost shell have an effect on the ionization energy as well. This effect, where the full positive charge of the nucleus is not felt by outer electrons due to the negative charges of inner electrons partially canceling out the positive charge, is called shielding. The more electrons shielding the outer electron shell from the nucleus, the less energy required to expel an electron from said atom. The higher the shielding effect the lower the ionization energy. It is because of the shielding effect that the ionization energy decreases from top to bottom within a group. From this trend, Cesium is said to have the lowest ionization energy and Fluorine is said to have the highest ionization energy (with the exception of Helium and Neon).


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