User:Graeme Bartlett/bromide hydride

Bromide hydrides are mixed anion compounds containing bromide (Br⁻) and hydride (H⁻) anions. Bromide hydrides may be cluster compounds, containing hydride atoms in a core, surrounded by a layer of metal atoms, encased in a shell of bromide ions. In Zr₂Br₂H the hydride is enclosed with tetrahedral coordination.^[1] Others may be transition metal complexes with hydrido ligands.^[1]

Bromide hydrides may be prepared by heating a metal hydride, with a metal bromide,^[2] or by heating a low valent metal bromide in hydrogen.

Related compounds include other halide hydrides like chloride hydrides and iodide hydrides.

^ ^a ^b Cite error: The named reference :0 was invoked but never defined (see the help page).
^ Reckeweg, Olaf; DiSalvo, Francis J. (2010-04-01). "New Calcium Hydride Halides with Familiar Structures. Syntheses and Crystal Structures of Ca 7 H 12 Cl 2 and Ca 2 H 3 Br". Zeitschrift für Naturforschung B. 65 (4): 493–498. doi:10.1515/znb-2010-0409. ISSN 1865-7117.

[:0-1] Cite error: The named reference :0 was invoked but never defined (see the help page).

[:1-2] Reckeweg, Olaf; DiSalvo, Francis J. (2010-04-01). "New Calcium Hydride Halides with Familiar Structures. Syntheses and Crystal Structures of Ca 7 H 12 Cl 2 and Ca 2 H 3 Br". Zeitschrift für Naturforschung B. 65 (4): 493–498. doi:10.1515/znb-2010-0409. ISSN 1865-7117.

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