4,4'-Methylenedianiline

4,4′-Methylenedianiline
Names
	Preferred IUPAC name 4,4′-Methylenedianiline
	Other names 4,4′-Diaminodiphenylmethane; 4,4′-Methylenebisbenzenamine; MDA; para,para′-Diaminodiphenylmethane; Dianilinomethane; 4,4′-Diphenylmethanediamine; Bis(4-aminophenyl)methane
Identifiers
CAS Number	101-77-9 ;
3D model (JSmol)	Interactive image;
ChEBI	CHEBI:32506 ;
ChEMBL	ChEMBL85728 ;
ChemSpider	7296 ;
ECHA InfoCard	100.002.705
EC Number	202-974-4;
KEGG	C14288 ;
PubChem CID	7577;
RTECS number	BY5425000;
UNII	GG5LL7OBZC ;
UN number	2651
CompTox Dashboard (EPA)	DTXSID6022422 ;
	InChI InChI=1S/C13H14N2/c14-12-5-1-10(2-6-12)9-11-3-7-13(15)8-4-11/h1-8H,9,14-15H2 Key: YBRVSVVVWCFQMG-UHFFFAOYSA-N ; InChI=1/C13H14N2/c14-12-5-1-10(2-6-12)9-11-3-7-13(15)8-4-11/h1-8H,9,14-15H2 Key: YBRVSVVVWCFQMG-UHFFFAOYAE;
	SMILES c1cc(N)ccc1Cc2ccc(N)cc2;
Properties
Chemical formula	C13H14N2
Molar mass	198.269 g·mol−1
Appearance	Colorless solid
Odor	faint, amine-like
Density	1.05 g/cm3 (100°C)
Melting point	89 °C (192 °F; 362 K)
Boiling point	398 to 399 °C (748 to 750 °F; 671 to 672 K)
Solubility in water	0.125 g/100 ml (20 °C)
Vapor pressure	0.0000002 mmHg (20°C)
Hazards
	Occupational safety and health (OHS/OSH):
Main hazards	potential carcinogen
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H317, H341, H350, H370, H373, H411
Precautionary statements	P201, P260, P273, P280, P308+P313
Flash point	190 °C; 374 °F; 463 K
	NIOSH (US health exposure limits):
PEL (Permissible)	TWA 0.010 ppm ST 0.100 ppm
REL (Recommended)	Ca
IDLH (Immediate danger)	Ca [N.D.]
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

4,4′-Methylenedianiline (MDA) is an organic compound with the formula CH₂(C₆H₄NH₂)₂. It is a colorless solid, although commercial samples can appear yellow or brown. It is produced on an industrial scale, mainly as a precursor to polyurethanes.

^ ^a ^b ^c ^d ^e ^f ^g NIOSH Pocket Guide to Chemical Hazards. "#0415". National Institute for Occupational Safety and Health (NIOSH).
^ ^a ^b Record of 4,4'-Diaminodiphenylmethane in the GESTIS Substance Database of the Institute for Occupational Safety and Health, accessed on 12 February 2021.

[PGCH-1] ^ ^a ^b ^c ^d ^e ^f ^g NIOSH Pocket Guide to Chemical Hazards. "#0415". National Institute for Occupational Safety and Health (NIOSH).

[GESTIS-2] Record of 4,4'-Diaminodiphenylmethane in the GESTIS Substance Database of the Institute for Occupational Safety and Health, accessed on 12 February 2021.

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