Pyrrhotite

Pyrrhotite
Brassy, tabular crystals of pyrrhotite, with sphalerite and quartz, from Nikolaevskiy Mine, Primorskiy Kray, Russia. Specimen size: 5.3 × 4.1 × 3.8 cm
General
CategoryMineral
Formula
(repeating unit)
Fe1−xS (x = 0 to 0.125)
IMA symbolPyh[1]
Strunz classification2.CC.10
Crystal systemMonoclinic, with hexagonal polytypes
Crystal classPrismatic (2/m)
(same H-M symbol)
Space groupA2/a
Unit cella = 11.88 Å, b = 6.87 Å,
c = 22.79 Å; β = 90.47°; Z = 26
Identification
ColorBronze, dark brown
Crystal habitTabular or prismatic in hexagonal prisms; massive to granular
CleavageAbsent
FractureUneven
Mohs scale hardness3.5 – 4.5
LusterMetallic
StreakDark grey – black
Specific gravity4.58 – 4.65, average = 4.61
Refractive indexOpaque
Fusibility3
SolubilitySoluble in hydrochloric acid
Other characteristicsWeakly magnetic, strongly magnetic on heating; non-luminescent, non-radioactive
References[2][3][4]

Pyrrhotite (pyrrhos in Greek meaning "flame-coloured") is an iron sulfide mineral with the formula Fe(1-x)S (x = 0 to 0.125). It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it is weakly magnetic. The magnetism decreases as the iron content increases, and troilite is non-magnetic.[5] Pyrrhotite is generally tabular and brassy/bronze in color with a metallic luster. The mineral occurs with mafic igneous rocks like norites, and may form from pyrite during metamorphic processes.[6] Pyrrhotite is associated and mined with other sulfide minerals like pentlandite, pyrite, chalcopyrite, and magnetite, and has been found globally.

NiAs structure of basic pyrrhotite-1C.
Pyrrhotite with pentlandite (late Paleoproterozoic, 1.85 G… | Flickr
Microscopic image of pyrrhotite under reflected light
  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Cite error: The named reference mindat was invoked but never defined (see the help page).
  3. ^ "Pyrrhotite" (PDF). Rruff.geo.arizona.edu. Retrieved 2015-07-10.
  4. ^ "Pyrrhotite Mineral Data". Webmineral.com. Retrieved 2015-07-10.
  5. ^ Haldar, S. K. (2017). Platinum-nickel-chromium deposits : geology, exploration and reserve base. Elsevier. p.12 ISBN 978-0-12-802041-8.
  6. ^ Cite error: The named reference Mauk was invoked but never defined (see the help page).

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