Deuterated chloroform

Deuterated chloroform
Stereo, skeletal formula of deuterated chloroform	Spacefill model of deuterated chloroform
Names
	IUPAC name trichloro(deuterio)methane
	Other names Chloroform-d; Deuterochloroform
Identifiers
CAS Number	865-49-6 ;
3D model (JSmol)	Interactive image;
Beilstein Reference	1697633
ChEBI	CHEBI:85365 ;
ChemSpider	64654 ;
ECHA InfoCard	100.011.585
EC Number	212-742-4;
PubChem CID	71583;
UNII	P1NW4885VT ;
UN number	1888
CompTox Dashboard (EPA)	DTXSID50904766 ;
	InChI InChI=1S/CHCl3/c2-1(3)4/h1H/i1D Key: HEDRZPFGACZZDS-MICDWDOJSA-N ; InChI=1/CHCl3/c2-1(3)4/h1H/i1D Key: HEDRZPFGACZZDS-MICDWDOJEH;
	SMILES [2H]C(Cl)(Cl)Cl;
Properties
Chemical formula	CDCl3
Molar mass	120.384 g/mol
Appearance	Colorless liquid
Odor	chloroform-like
Density	1.500 g/cm3
Melting point	−64 °C (−83 °F; 209 K)
Boiling point	61 °C (142 °F; 334 K)
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H302, H315, H319, H331, H336, H351, H361, H372, H373
Precautionary statements	P201, P202, P260, P261, P264, P270, P271, P280, P281, P301+P312, P302+P352, P304+P340, P305+P351+P338, P308+P313, P311, P312, P314, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, P501
NFPA 704 (fire diamond)	2 0 0
Related compounds
Related compounds	Chloroform; Deuterated dichloromethane
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). verify (what is ?) Infobox references

Deuterated chloroform, also known as chloroform-d, is the organic compound with the formula CDCl₃. Deuterated chloroform is a common solvent used in NMR spectroscopy.^[2] The properties of CDCl₃ and ordinary CHCl₃ (chloroform) are virtually identical.

Deuterochloroform was first made in 1935 during the years of research on deuterium.^[3]

^ "Chloroform-d".
^ Fulmer, Gregory R.; Miller, Alexander J. M.; Sherden, Nathaniel H.; Gottlieb, Hugo E.; Nudelman, Abraham; Stoltz, Brian M.; Bercaw, John E.; Goldberg, Karen I. (2010). "NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist" (PDF). Organometallics. 29 (9): 2176–2179. doi:10.1021/om100106e.
^ Chloroform-d (Deuteriochloroform), F. W. Breuer , J. Am. Chem. Soc. 1935, 57, 11, 2236–2237 (November 1, 1935) [1]

[1] "Chloroform-d".

[2] Fulmer, Gregory R.; Miller, Alexander J. M.; Sherden, Nathaniel H.; Gottlieb, Hugo E.; Nudelman, Abraham; Stoltz, Brian M.; Bercaw, John E.; Goldberg, Karen I. (2010). "NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist" (PDF). Organometallics. 29 (9): 2176–2179. doi:10.1021/om100106e.

[3] Chloroform-d (Deuteriochloroform), F. W. Breuer , J. Am. Chem. Soc. 1935, 57, 11, 2236–2237 (November 1, 1935) [1]

[1]

[2]

[3]